London Clay;
kaolin;
low-grade bauxite;
belite-ye'elimite-ferrite cements;
hydration;
compressive strength;
UN SDG 13;
RAW MIX DESIGN;
EARLY HYDRATION;
CHEMISTRY;
WATER;
D O I:
10.1680/jadcr.23.00239
中图分类号:
TU [建筑科学];
学科分类号:
0813 ;
摘要:
London Clay (LC) is generated in significant quantities from major infrastructure development projects within and around London. Excavated LC spoils are typically landfilled or used for landscaping purposes with minimal value. This study investigates the feasibility of producing belite-ye'elimite-ferrite (BYF) cements using London Clay (LC) in combination with kaolin or low-grade bauxite. Six cement clinkers with varying compositions were synthesised at 1300 degrees C. The phase composition of the synthesised clinkers was quantified using XRD coupled with Rietveld refinement. The hydration behaviour, phase assemblage evolution, and mechanical performance of the cements were examined using isothermal calorimetry, XRD, TGA, and compressive strength testing respectively, up to 90 days of curing. It is demonstrated that LC can be used either on its own or with kaolin or low-grade bauxite to produce BYF cements with a wide range of composition: 31 to 64 wt.% belite, 9.3 to 27 wt.% ye'elimite and 2.1 to 31% ferrite. The use of LC as the sole alumina source resulted in low compressive strength at early stages. Nevertheless, the strength developed over time, reaching 27.8 MPa at 90 d (0.5 w/b). Possible approaches to develop LC further for producing viable BYF cements are discussed.
机构:
Slovenian Natl Bldg & Civil Engn Inst, Dimiceva Ulica 12, Ljubljana 1000, Slovenia
Jozef Stefan Int Postgrad Sch, Jamova Cesta 39, Ljubljana 1000, SloveniaSlovenian Natl Bldg & Civil Engn Inst, Dimiceva Ulica 12, Ljubljana 1000, Slovenia
Mrak, Marusa
Winnefeld, Frank
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Empa, Swiss Fed Labs Mat Sci & Technol, Uberlandstr 129, CH-8600 Dubendorf, SwitzerlandSlovenian Natl Bldg & Civil Engn Inst, Dimiceva Ulica 12, Ljubljana 1000, Slovenia
Winnefeld, Frank
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Lothenbach, Barbara
Legat, Andraz
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Slovenian Natl Bldg & Civil Engn Inst, Dimiceva Ulica 12, Ljubljana 1000, SloveniaSlovenian Natl Bldg & Civil Engn Inst, Dimiceva Ulica 12, Ljubljana 1000, Slovenia
Legat, Andraz
Dolenec, Sabina
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Slovenian Natl Bldg & Civil Engn Inst, Dimiceva Ulica 12, Ljubljana 1000, SloveniaSlovenian Natl Bldg & Civil Engn Inst, Dimiceva Ulica 12, Ljubljana 1000, Slovenia
机构:
Israel Inst Technol, Natl Bldg Res Inst, Fac Civil & Environm Engn Technion, Haifa, IsraelIsrael Inst Technol, Natl Bldg Res Inst, Fac Civil & Environm Engn Technion, Haifa, Israel
机构:
LafargeHolcim Res Ctr, 95 Rue Montmurier, F-38291 St Quentin Fallavier, France
Univ Joseph Fourier, Univ Savoie, Grenoble INP, LEPMI,UMR5279,CNRS, 1130 Rue Piscine,BP 75, F-38402 St Martin Dheres, FranceLafargeHolcim Res Ctr, 95 Rue Montmurier, F-38291 St Quentin Fallavier, France
Koga, Guilherme Yuuki
Albert, Blandine
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LafargeHolcim Res Ctr, 95 Rue Montmurier, F-38291 St Quentin Fallavier, FranceLafargeHolcim Res Ctr, 95 Rue Montmurier, F-38291 St Quentin Fallavier, France
Albert, Blandine
Roche, Virginie
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Univ Joseph Fourier, Univ Savoie, Grenoble INP, LEPMI,UMR5279,CNRS, 1130 Rue Piscine,BP 75, F-38402 St Martin Dheres, FranceLafargeHolcim Res Ctr, 95 Rue Montmurier, F-38291 St Quentin Fallavier, France
Roche, Virginie
Nogueira, Ricardo Pereira
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Univ Joseph Fourier, Univ Savoie, Grenoble INP, LEPMI,UMR5279,CNRS, 1130 Rue Piscine,BP 75, F-38402 St Martin Dheres, France
Khalifa Univ Sci & Technol, Gas Res Ctr, POB 2533, Abu Dhabi, U Arab EmiratesLafargeHolcim Res Ctr, 95 Rue Montmurier, F-38291 St Quentin Fallavier, France