Photoactivable malachite green-based alkynylplatinum(II) 2,6-bis(N-alkylbenzimidazol-2-yl)pyridine complexes

被引：0
|
作者：
Cheung, Andy Shun-Hoi [1 ]
Leung, Ming-Yi [1 ]
Fung, Tony Ho-Ching [1 ]
Yam, Vivian Wing-Wah [1 ]
机构：
[1] Univ Hong Kong, Inst Mol Funct Mat, Pokfulam Rd, Hong Kong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 77期
关键词：
ALPHA-DIIMINE LIGANDS; CENTER-DOT-METAL; PLATINUM(II) COMPLEXES; ELECTRONIC-SPECTRA; TERPYRIDYL COMPLEXES; CATION COMPLEXATION; PI-PI; PHOTOPHYSICS; TRANSITION; PHOTOCHROMISM;
D O I：
10.1039/d4cc03558e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(II) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and pi-pi stacking interactions, have been observed before and after photo-irradiation.
引用
收藏
页码：10676 / 10679
页数：5
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