Photoactivable malachite green-based alkynylplatinum(II) 2,6-bis(N-alkylbenzimidazol-2-yl)pyridine complexes

被引：0

作者：

Cheung, Andy Shun-Hoi ^{[1
]}

Leung, Ming-Yi ^{[1
]}

Fung, Tony Ho-Ching ^{[1
]}

Yam, Vivian Wing-Wah ^{[1
]}

机构：

[1] Univ Hong Kong, Inst Mol Funct Mat, Pokfulam Rd, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 77期

关键词：

ALPHA-DIIMINE LIGANDS; CENTER-DOT-METAL; PLATINUM(II) COMPLEXES; ELECTRONIC-SPECTRA; TERPYRIDYL COMPLEXES; CATION COMPLEXATION; PI-PI; PHOTOPHYSICS; TRANSITION; PHOTOCHROMISM;

D O I：

10.1039/d4cc03558e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(II) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and pi-pi stacking interactions, have been observed before and after photo-irradiation.

引用

页码：10676 / 10679

页数：5

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