Preparation of SrVO3 by annealing of Sr2V2O7 in a reducing atmosphere

被引:0
|
作者
Lee, Edward [1 ]
Harris, Richard A. [1 ]
Terblans, Jacobus J. [1 ]
Coetsee, Elizabeth [1 ]
Kumar, Vinay [1 ,2 ]
Swart, Hendrik C. [1 ]
机构
[1] Univ Free State, Dept Phys, POB 339, ZA-9300 Bloemfontein, South Africa
[2] Cent Univ Jammu, Dept Phys & Astron Sci, Samba 181143, India
来源
CHEMICAL PHYSICS IMPACT | 2024年 / 9卷
基金
新加坡国家研究基金会;
关键词
SrVO3; X-ray photoelectron spectroscopy; Vanadium; ELECTRICAL-CONDUCTIVITY; THIN-FILMS;
D O I
10.1016/j.chphi.2024.100715
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study focuses on the synthesis of SrVO3 3 through the reduction of Sr2V2O7 2 V 2 O 7 by annealing in a reducing atmosphere. The effects of annealing temperature and annealing duration on Sr2V2O7 2 V 2 O 7 were investigated. The X-ray powder diffraction pattern showed that stoichiometric changes to Sr2V2O7 2 V 2 O 7 were achieved only at an elevated annealing temperature of 1000 degrees C in a reducing atmosphere, and that the desired SrVO3 3 was obtained only after 144 h of annealing. Further investigation of SrVO3 3 was performed using X-ray photoelectron spectroscopy, which confirmed that the reduction of V 5+ found in Sr2V2O7 2 V 2 O 7 to V 4+ found in SrVO3 3 was achieved.
引用
收藏
页数:5
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