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Highly Efficient, Iodine-Free Dye-Sensitized Solar Cells with Solid-State Synthesis of Conducting Polymers
被引:182
|作者:
Koh, Jong Kwan
[1
]
Kim, Jeonghun
[1
]
Kim, Byeonggwan
[1
]
Kim, Jong Hak
[1
]
Kim, Eunkyoung
[1
]
机构:
[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
关键词:
TITANIUM-DIOXIDE FILMS;
CHARGE RECOMBINATION;
HOLE CONDUCTORS;
MESOPOROUS TIO2;
NANOCRYSTALLINE;
POLY(3,4-ETHYLENEDIOXYTHIOPHENE);
ELECTROLYTE;
KINETICS;
ANIONS;
OXIDE;
D O I:
10.1002/adma.201004715
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A solid-state polymerizable conductive monomer with good conductivity and penetration to the photoelectrode is introduced to iodine-free, solid-state dye-sensitized solar cells (DSSCs) using an easily accessible and widely applicable fabrication method. A conducting polymer as a hole transporting material effectively penetrates into the TiO2 pores and polymerizes with heating to mild temperatures. The fabricated DSSCs exhibited the highest energy conversion efficiency of 5.4% in N719 dye.
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页码:1641 / +
页数:7
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