Efficient electrochemical degradation of TBP using a Ti/SnO 2-Sb/ F-PbO 2 electrode

被引:1
|
作者
Wei, Xing-Peng [1 ]
Ni, Hong-Gang [1 ]
机构
[1] Peking Univ, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
关键词
Electrochemical method; TBP; Ti/SnO; 2-Sb/F-PbO; 2; electrode; Oxidation; Multilayer structure; Composite materials; TRIBUTYL-PHOSPHATE DEGRADATION; BIODEGRADATION;
D O I
10.1016/j.matlet.2024.136474
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A Ti/SnO 2 -Sb/F-PbO 2 electrode was applied to electrochemically oxidize tributyl phosphate (TBP). Under the optimal conditions, TBP removal reached 82.4 % in 80 min with an energy efficiency of 82.6 g kWh -1 . This method overcame some TBP biodegradation 's flaws such as narrow initial treating concentrations range and time- consuming. The degradation energy efficiency of our method ranges from 34.4 g kWh -1 to 379 g kWh -1 at different initial concentrations (0.5 -5.0 g/L), which is also far higher than that of a previous electrochemical treatment of TBP (0.13 g kWh -1 ).
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页数:4
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