Low-temperature aqueous synthesis and biocompatibility of manganese whitlockite

被引：0

作者：

Kizalaite, Agne ^{[1
]}

Dubnika, Arita ^{[2
,3
]}

Antuzevics, Andris ^{[1
,4
]}

Murauskas, Tomas ^{[1
]}

Stewart Jr, Orlando ^{[5
]}

Stoll, Sarah L. ^{[5
]}

Goto, Tomoyo ^{[6
,7
]}

Sekino, Tohru ^{[6
]}

Zarkov, Aleksej ^{[1
]}

机构：

[1] Vilnius Univ, Inst Chem, Naugarduko 24, LT-03225 Vilnius, Lithuania

[2] Riga Tech Univ, Inst Biomat & Bioengn, Fac Nat Sci & Technol, Pulka 3, LV-1007 Riga, Latvia

[3] Riga Tech Univ, Balt Biomat Ctr Excellence, LV-1658 Riga, Latvia

[4] Univ Latvia, Inst Solid State Phys, Kengaraga 8, LV-1063 Riga, Latvia

[5] Georgetown Univ, Dept Chem, 37th & O St NW, Washington, DC 20057 USA

[6] Osaka Univ, SANKEN Inst Sci & Ind Res, 8-1 Mihogaoka, Osaka, Ibaraki 5670047, Japan

[7] Osaka Univ, Inst Adv Cocreat Studies, 1-1 Yamadaoka, Suita, Osaka 5650871, Japan

来源：

CERAMICS INTERNATIONAL | 2024年 / 50卷 / 16期

关键词：

Manganese whitlockite; Ca18Mn2(HPO4)2(PO4)12; Dissolution-precipitation; Cell viability; CRYSTAL-STRUCTURE; LUMINESCENT PROPERTIES; MAGNESIUM WHITLOCKITE; CALCIUM; HYDROXYAPATITE; ANTIBACTERIAL; BIOMATERIALS;

D O I：

10.1016/j.ceramint.2024.05.157

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this work, manganese whitlockite (Mn-WH, Ca 18 Mn 2 (HPO 4 ) 2 (PO 4 ) 12 ) was successfully synthesized and comprehensively characterized. This material is a manganese-containing analog of the biomineral magnesium whitlockite (Mg-WH, Ca 18 Mg 2 (HPO 4 ) 2 (PO 4 ) 12 ). The synthesis was performed via a low-temperature dissolutionprecipitation process in aqueous medium under ambient pressure at 75 degrees C using dicalcium phosphate dehydrate and manganese acetate tetrahydrate as starting materials. The crystal structure of the synthesized powder was determined by powder X-ray diffraction, FTIR and Raman spectroscopies, demonstrating the presence of characteristic structural units. Morphological features and elemental distribution within the synthesized powder were studied by SEM/EDX analysis. XPS, EPR and magnetic studies confirmed the presence of Mn ions in a divalent state. Temperature-dependent magnetic measurements revealed a paramagnetic behavior of Mn-WH down to 5 K. In vitro cytotoxicity experiments were performed with MC3T3-E1 preosteoblastic cell line.

引用

页码：28490 / 28497

页数：8

共 50 条

[21] LOW-TEMPERATURE ALLOY SYNTHESIS
HOLT, EL
NATURE, 1964, 203 (494) : 857 - &
[22] LOW-TEMPERATURE SYNTHESIS OF CERAMICS
SHEPPARD, LM
ADVANCED MATERIALS & PROCESSES, 1986, 130 (05): : 47 - 51
[23] LOW-TEMPERATURE SYNTHESIS OF POWELLITE
ZHILTSOV.IG
KARPOVA, LN
SIDORENK.GA
VALUYEVA, AA
DARA, AD
GEOCHEMISTRY INTERNATIONAL USSR, 1969, 6 (01): : 104 - &
[24] Low-Temperature Synthesis of Graphene
Novikov, V. P.
Kirik, S. A.
TECHNICAL PHYSICS LETTERS, 2011, 37 (06) : 565 - 567
[25] Low-temperature hydrothermal synthesis of spinel-type lithium manganese oxide nanocrystallites
Zhang, YC
Wang, H
Xu, HY
Wang, B
Yan, H
Ahniyaz, A
Yoshimura, M
SOLID STATE IONICS, 2003, 158 (1-2) : 113 - 117
[26] THE LOW-TEMPERATURE SYNTHESIS OF THALLIUM MINERALS IN AQUEOUS ENVIRONMENT IN RELATION TO NATURAL OCCURRENCES
ELHADDAD, MA
MOH, GH
NEUES JAHRBUCH FUR MINERALOGIE-ABHANDLUNGEN, 1993, 166 (01): : 9 - 14
[27] Low-temperature synthesis of bismuth titanate by an aqueous sol-gel method
Du, Xianfeng
Xu, Youlong
Ma, Hanxiao
Wang, Jie
Li, Xifei
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (07) : 2079 - 2082
[28] LOW-TEMPERATURE SPECIFIC HEAT ANOMALY IN MANGANESE FERRITES
LOW, B
JOURNAL OF APPLIED PHYSICS, 1963, 34 (04) : 1250 - &
[29] MECHANISM OF LOW-TEMPERATURE REDUCTION OF MANGANESE OXIDES WITH HYDROGEN
PAVLOVAV.AI
KHOMYAKO.KG
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR, 1966, 40 (08): : 936 - &
[30] Energetics of low-temperature polymorphs of manganese dioxide and oxyhydroxide
Fritsch, S
Post, JE
Navrotsky, A
GEOCHIMICA ET COSMOCHIMICA ACTA, 1997, 61 (13) : 2613 - 2616

← 1 2 3 4 5 →