Novel semi-aromatic polyesters based on the biobased diol 2,2′-((3S,3aR,6S,6aR)-hexahydrofuro[3,2-b]furan-3,6-diyl)bis(ethan-1-ol): synthesis, characterization and properties

被引：0

作者：

Xu, Huixuan ^{[1
]}

Sun, Weigang ^{[1
]}

Wei, Zhonglin ^{[1
]}

Cao, Jungang ^{[1
]}

Liang, Dapeng ^{[1
]}

Lin, Yingjie ^{[1
]}

Duan, Haifeng ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China

来源：

POLYMER CHEMISTRY | 2024年 / 15卷 / 25期

关键词：

SOLID-STATE MODIFICATION; MELTING BEHAVIOR; COPOLYESTERS; ISOSORBIDE;

D O I：

10.1039/d4py00011k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Herein, we provide details of the synthesis and characterization of a novel 2-carbon-extended diol derived from isomannide, 2,2 '-((3S,3aR,6S,6aR)-hexahydrofuro[3,2-b]furan-3,6-diyl)bis(ethan-1-ol) and the corresponding semi-aromatic copolyester (PIeT) based on it and dimethyl terephthalate. This new polyester (PIeT) has a weight-average molecular weight of about 40 000 g mol(-1). The NMR analysis showed that the isohexide unit was retained under applied conditions. DSC and WAXD analyses demonstrated that the polyester is semicrystalline.

引用

页码：2590 / 2597

页数：8

共 14 条

[11] Crystal structure of (1′R*,2R*,3aR*,6aS*,6S*)-2,6-(1′-acetoxyundecano)-4-oxo-hexahydro[3,4-b]furan, C19H30O5
Peters, K
Peters, EM
Salzbrenner, C
Tochtermann, W
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1998, 213 (01): : 101 - 102
[12] GRADIENT HIGH PERFORMANCE LIQUID CHROMATOGRAPHY METHOD FOR DETERMINATION OF RELATED SUBSTANCES IN [(3aS, 4R, 6aR)-2, 3, 3a, 4, 5, 6a-HEXAHYDROFURO [2, 3-b] FURAN-4-YL] N-[(2S, 3R)-4-[(4-AMINOPHENYL) SULFONYL-(2-METHYLPROPYL) AMINO]-3-HYDROXY-1-PHENYLBUTAN-2YL] CARBAMATE DOSAGE FORM
Kumar, B. Karuna
Sekaranand, V. Guna
Shekar, K. B. Chandra
INTERNATIONAL JOURNAL OF PHARMACEUTICAL SCIENCES AND RESEARCH, 2019, 10 (12): : 5673 - 5682
[13] Novel bridgehead nitrogen heterocyclic systems:: Synthesis and antimicrobial activity of imidazo[2,1-b]-1,3,4-thiadiazolo[2,3-c]-s-triazoles, s-triazolo[3,4-b][1,3,4]thiadiazolo[3,2-b]imidazo[4,5-b] quinoxaline and bis-(s-triazolo[3,4-b][1,3,4]thiadiazolo[3,2-b] [imidazo[4,5-b]-cyclohexane]-5a, 6a-diene)
Mohan, J
Anupama
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2001, 40 (04): : 303 - 306
[14] Synthesis and [4+2] cycloaddition of (2R,2′R)-N,N′-fumaroylbis[fenchane-8,2-sultam] (= (2E)-1,4-bis[(3aS,6S,7aR)-1,4,5,6,7,7a-hexahydro-7,7-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzothiazol-1-yl]but-2-ene-1,4-dione) to cyclopentadiene
Piatek, AM
Chojnacka, A
Chapuis, C
Jurczak, J
HELVETICA CHIMICA ACTA, 2005, 88 (09) : 2441 - 2453

← 1 2 →