Construction of a stable radical hydrogen-bonded metal-organic framework with functionalized tetrathiafulvalene linkers

被引：0
|
作者：
Su, Jian [1 ,2 ]
Han, Xiao [1 ]
Ke, Si-Wen [1 ]
Zhou, Xiao-Cheng [1 ]
Yuan, Shuai [1 ]
Ding, Mengning [1 ]
Zuo, Jing-Lin [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China
[2] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 45期
基金：
中国国家自然科学基金;
关键词：
ELECTRICAL-CONDUCTIVITY; MOF;
D O I：
10.1039/d4cc01152j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A stable two-dimensional radical hydrogen-bonded metal-organic framework, constructed using a modified tetrathiafulvalene-tetrabenzoate ((2-Me)-H4TTFTB) linker and Cd2+ ions, exhibits a high electrical conductivity of 4.1 x 10-4 S m-1 and excellent photothermal conversion with a temperature increase of 137 degrees C in 15 s under the irradiation of a 0.7 W cm-2 808 nm laser. We have designed a radical hydrogen-bonded metal-organic framework with an atomically-resolved single crystal structure, demonstrating excellent stability, good electrical conductivity, and highly efficient near-infrared photothermal conversion.
引用
收藏
页码：5812 / 5815
页数：4
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