Construction of a stable radical hydrogen-bonded metal-organic framework with functionalized tetrathiafulvalene linkers

被引：0

作者：

Su, Jian ^{[1
,2
]}

Han, Xiao ^{[1
]}

Ke, Si-Wen ^{[1
]}

Zhou, Xiao-Cheng ^{[1
]}

Yuan, Shuai ^{[1
]}

Ding, Mengning ^{[1
]}

Zuo, Jing-Lin ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210023, Peoples R China

[2] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 45期

基金：

中国国家自然科学基金;

关键词：

ELECTRICAL-CONDUCTIVITY; MOF;

D O I：

10.1039/d4cc01152j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stable two-dimensional radical hydrogen-bonded metal-organic framework, constructed using a modified tetrathiafulvalene-tetrabenzoate ((2-Me)-H4TTFTB) linker and Cd2+ ions, exhibits a high electrical conductivity of 4.1 x 10-4 S m-1 and excellent photothermal conversion with a temperature increase of 137 degrees C in 15 s under the irradiation of a 0.7 W cm-2 808 nm laser. We have designed a radical hydrogen-bonded metal-organic framework with an atomically-resolved single crystal structure, demonstrating excellent stability, good electrical conductivity, and highly efficient near-infrared photothermal conversion.

引用

页码：5812 / 5815

页数：4

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