Synthesis and characterization of ZnCo2O4 nanocomposites with enhanced electrochemical features for supercapacitor applications

被引:3
|
作者
Mathivanan, Agalya [1 ]
Jothibas, M. [1 ]
Nesakumar, Noel [2 ]
机构
[1] Bharathidasan Univ Tiruchirappalli, TBML Coll, PG & Res Dept Phys, Porayar 609307, Tamil Nadu, India
[2] SASTRA Deemed Be Univ, Sch Chem & Biotechnol, Thanjavur 613401, Tamil Nadu, India
关键词
Hydrothermal; Three electrode system; Cubic structure; Specific capacitance and electrochemical applications; ELECTRODE MATERIAL; OXYGEN REDUCTION; PERFORMANCE; SPINEL; NANOPARTICLES; HYBRID; MICROFLOWERS; MORPHOLOGY; NANOSHEETS; GRAPHENE;
D O I
10.1016/j.surfin.2024.104443
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Supercapacitors have recently emerged as a promising alternative to conventional batteries due to their improved energy storage capabilities. The optical, electrochemical, and structural properties of ZnCo2O4 nanocomposites produced by hydrothermal synthesis are detailed in this study. In order to study the physicochemical properties of the synthesized goods, the created nanocomposite samples were analyzed using XRD, FTIR, UV-Vis, SEM with EDAX, HR-TEM, BET, XPS, and charge storage potential. Crystallite size was found to be inversely proportional to increasing range of 5.01 nm to 10.62 nm in the XRD data, which compared the cubic structure. Electron microscopy and high-resolution transmission electron microscopy (HR-TEM) indicated a morphological shift indicative of improved electrochemical capabilities. The absorption research showed that different molar ratios were successful in increasing the optical bandgap from zero to 1.93 eV, whereas functional component adsorption lowered it from 2.35 eV. A maximum specific capacitance of 383.3 Fg(-1) was determined by the electrochemical research, which indicated an inherent pseudo capacitance. Experimental results show that the ZnCo2O4 nanocomposite can effectively store charges, which is in line with expectations given its high capacitance and very inexpensive production.
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页数:18
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