Redox Reactions of Organic Molecules Using Rotating Magnetic Field and Metal Rods

被引：4

作者：

Liu, Haodong ^{[1
]}

Han, Xuliang ^{[1
]}

Feng, Xiaomei ^{[1
]}

Zhang, Lizhi ^{[1
]}

Sun, Fenggang ^{[1
]}

Jia, Fuchao ^{[2
]}

Zhao, Zengdian ^{[1
]}

Liu, Hui ^{[1
]}

Li, Xinjin ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Chem & Chem Engn, Zibo 255000, Shandong, Peoples R China

[2] Shandong Univ Technol, Sch Phys & Optoelelctron Engn, Zibo 255000, Shandong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2024年 / 146卷 / 26期

基金：

中国国家自然科学基金;

关键词：

CATALYTIC HYDROTRIFLUOROMETHYLATION; TRIFLUOROMETHYLATION; ELECTRON; ALKENES;

D O I：

10.1021/jacs.4c05987

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In recent years, redox reactions have harnessed light or mechanical energy to enable the formation of chemical bonds. We postulated a complementary approach that electromagnetic induction could promote the redox reaction of organic molecules using a rotating magnetic field and metal rods. Here, we report that electromotive force activates the redox-active trifluoromethylating reagents. This magnetoredox system can be applied to the trifluoromethylation of heteroarenes with high regioselectivity and hydrotrifluoromethylation of alkenes without the need for catalysts and organic additives.

引用

页码：18143 / 18150

页数：8

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