A Three-Dimensional Open-Framework Tin(II) Sulfate with Near-Unity Photoluminescence Quantum Yield

被引：1

作者：

Wen, Xuemei ^{[1
]}

Wang, Jing ^{[1
]}

Zhang, Zhizhuan ^{[1
]}

Han, Xiangyu ^{[1
]}

Zeng, Hongmei ^{[1
]}

Zou, Guohong ^{[1
]}

Xu, Dingguo ^{[1
]}

Lin, Zhien ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China

来源：

INORGANIC CHEMISTRY | 2024年 / 63卷 / 19期

基金：

中国国家自然科学基金;

关键词：

WHITE-LIGHT; ZINC PHOSPHATE; ZEOLITE; ALUMINOBORATE; EMISSION;

D O I：

10.1021/acs.inorgchem.4c00943

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new open-framework tin(II) sulfate, formulated as C4H12N2<middle dot>Sn(SO4)(2)<middle dot>H2O, was prepared under the structure-directing effect of piperazine. This compound features a 3D structure with 16-ring channels. Under ultraviolet light irradiation, it emits bright yellow luminescence with a near-unity photoluminescence quantum yield. Theoretical calculations were carried out to understand the luminescence mechanism.

引用

页码：8521 / 8525

页数：5

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