Organic Acid-Assisted Preparation of Hydroxyapatite-Supported Ni Catalysts for Arene Hydrogenation

被引:0
|
作者
Duan, Chengjie [1 ]
Li, Kun [1 ]
Ye, Wenbo [2 ,3 ]
Mao, Weitao [2 ]
He, Guangke [1 ]
Liu, Xiang [1 ,2 ,3 ]
机构
[1] Nanjing Tech Univ, Sch Chem & Mol Engn, Nanjing 211816, Peoples R China
[2] Zhejiang Univ, Coll Chem & Biol Engn, Hangzhou 310027, Peoples R China
[3] Univ Quzhou, Inst Zhejiang, Quzhou 324000, Peoples R China
基金
中国国家自然科学基金;
关键词
non-noble metal catalysis; arene hydrogenation; supported nickel catalyst; organic acid-assisted impregnation; hydroxyapatite; SELECTIVE HYDROGENATION; NICKEL; NANOPARTICLES; REDUCTION; EFFICIENT; BENZENE; CARBON;
D O I
10.1002/cctc.202400208
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Developing non-noble metal catalysts that can efficiently and selectively hydrogenate arenes remains a significant challenge. In this study, we developed efficient Ni catalysts for the arene hydrogenation based on an organic acid-regulated impregnation strategy. These easily accessible Ni catalysts demonstrated exceptional efficiency, selectivity, reusability, and good substrate compatibility. The influence of carbon chain lengths and side-chain hydroxyl or amino groups on dicarboxylic acids used in the catalyst preparation was comprehensively investigated. Characterizations and kinetic studies demonstrated the influence of organic acids on the size of Ni nanoparticles, the proportion of metallic nickel, and the strength of surface acidity. These factors influenced the activation of arene and hydrogen, thereby affecting the hydrogenative activity. Notably, hydroxyapatite-supported Ni catalyst, assisted by tartaric acid (Ni-TA/HAP) with an appropriate tartaric acid-to-nickel ratio, resulted in relatively smaller Ni nanoparticles, an increased proportion of Ni0, and more acidic sites, thereby exhibiting the best hydrogenation performance. Exploring the impact of structural variations in organic acids on catalyst properties unveils crucial insights for enhancing arene hydrogenative activity. The Ni catalyst, supported by hydroxyapatite and aided by a hydroxy-dicarboxylic acid (tartaric acid) with an optimal ratio, resulted in relatively smaller Ni nanoparticles, a higher Ni0 proportion, and increased acidic sites, showcasing exceptional hydrogenation performance. image
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页数:11
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