Preparation of Li2+xInxZn1-xCl4+2x (0 ≤ x ≤ 0.5) solid electrolyte and its application in all-solid-state Li-ion batteries

被引:3
|
作者
Nguyet, Nguyen Thi Minh [1 ,2 ]
Toan, Tran Viet [2 ,3 ]
Anh, Luu Tuan [2 ,3 ]
Anh, Luong Thi Quynh [2 ,3 ]
Tu, Tran Anh [1 ,2 ,3 ]
Phuc, Nguyen Huu Huy [1 ,2 ,3 ]
机构
[1] Ho Chi Minh City Univ Technol HCMUT, VNU HCM Key Lab Mat Technol, 268 Ly Thuong Kiet Str,Dist 10, Ho Chi Minh City, Vietnam
[2] Vietnam Natl Univ Ho Chi Minh City, Ho Chi Minh City, Vietnam
[3] Ho Chi Minh City Univ Technol HCMUT, Fac Mat Technol, 268 Ly Thuong Kiet Str,Dist 10, Ho Chi Minh City, Vietnam
来源
MATERIALS ADVANCES | 2024年 / 5卷 / 18期
关键词
CONDUCTORS; PROGRESS;
D O I
10.1039/d4ma00405a
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Li2+xInxZn1-xCl4+2x (0 <= x <= 0.5) solid electrolytes were synthesized using a mechanochemical method. XRD indicated that the prepared samples had a cubic structure. The lattice parameter was dependent on the value of x. The cold-pressed pellet of the sample with x = 0.45 had an ionic conductivity of about 2.4 x 10(-4) S cm(-1) at 25 degrees C and an activation energy of about 0.446 eV. The equivalence circuit and distribution of the relaxation time indicated that grain boundary resistance was the main component of the total resistance of the sample. The hot-pressed pellet of the sample with x = 0.45 had an ionic conductivity of about 9.2 x 10(-4) S cm(-1) at 25 degrees C and an activation energy of about 0.300 eV, which were comparable with those of the reported halide-based solid electrolyte. The solid-state cell employing the sample with x = 0.45 as a solid electrolyte and bare LiNi0.5Mn0.3Co0.2O2 as the active material showed good cyclic ability at room temperature.
引用
收藏
页码:7222 / 7229
页数:8
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