Transformation of furfural into dimorpholinocyclopentenone using Al-SBA-15 materials

被引：2

作者：

Fernandez, Miriam Lopez ^{[1
]}

Len, Thomas ^{[1
]}

Urbano, Juan ^{[2
,3
]}

Balu, Alina ^{[1
]}

Luque, Rafael ^{[4
,5
]}

机构：

[1] Univ Cordoba, Dept Quim Organ, Inst Quim Fina & Nanoquim, Campus Rabanales,Edificio Marie Curie C-3,Ctra Nna, E-14014 Cordoba, Spain

[2] Univ Huelva, Lab Sustainable & Circular Technol CIDERTA, Fac Expt Sci, Campus El Carmen, Huelva 21071, Spain

[3] Univ Huelva, Fac Expt Sci, Chem Dept, Campus El Carmen, Huelva 21071, Spain

[4] Natl Univ Sci & Technol Polytehn Bucharest, 1-7 Gheorghe Polizu Str, Bucharest, Romania

[5] Univ ECOTEC, Km 13-5 Samborondon,EC092302, Samborondon, Ecuador

来源：

SUSTAINABLE CHEMISTRY AND PHARMACY | 2024年 / 39卷

关键词：

Furfural; Morpholine; Cyclopentenone; Al-SBA-15; Cyclization rearrangement; CATALYTIC-PROPERTIES; SBA-15; SILICA; CYCLOPENTENONE DERIVATIVES; ACID; REARRANGEMENT; CYCLOPENTANONE; HYDROGENATION; CONVERSION; DEHYDRATION; ALCOHOL;

D O I：

10.1016/j.scp.2024.101573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimorpholinocyclopentenone, being a relevant chemical compound widespread employed in the pharmaceutical industry, can be synthesized by a facile chemically catalyzed conversion reaction between furfural and morpholine. This reaction was investigated in this work by employing a simple, affordable non -noble metal mesoporous Al -SBA -15 with improved catalytic activity and superior product selectivity. The prepared materials shown a mesoporous structure with high pore volume and enlarged surface area, which are impacted by the quantity of aluminium atom incorporated. These differences leading to superior catalytic properties of Al -SBA -15 with a Si/Al ratio of 10.

引用

页数：8

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