A one-pot approach towards polycarbonate-b-polyester block copolymers via chemoselective polymerization catalyzed by a one-component phosphonium borane Lewis pair

被引：4

作者：

Li, Yutao ^{[1
]}

Kou, Xinhui ^{[2
]}

Wang, Xiaowu ^{[3
]}

Xia, Lin ^{[1
]}

Li, Zhibo ^{[1
,3
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Polymer Sci & Engn, 53 Zhengzhou Rd, Qingdao 266042, Peoples R China

[2] Qingdao Univ Sci & Technol, Anal & Testing Ctr, 53 Zhengzhou Rd, Qingdao 266042, Peoples R China

[3] Qingdao Univ Sci & Technol, Coll Chem Engn, 53 Zhengzhou Rd, Qingdao 266042, Peoples R China

来源：

POLYMER CHEMISTRY | 2024年 / 15卷 / 24期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

ABA BLOCK; ONE-STEP; EPOXIDES; ANHYDRIDE; MIXTURES; LACTIDE; ROUTE; CO2;

D O I：

10.1039/d4py00329b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Chemoselective polymerization from mixtures of monomers to control the polymer sequence is a challenging task. In this contribution, we describe a unique chemoselective polymerization affording predictable (co)polymer compositions from a mixture of monomers. The use of a one-component phosphonium borane Lewis pair and a mixture of l-lactide (l-LA), cyclohexene oxide (CHO) and CO2 enables the selective synthesis of either a polyester, polycarbonate or poly(carbonate-b-ester). The selectivity depends on the nature of the borane-oxygen functionality at the growing polymer chain end, and can be controlled by the addition of CO2 as an exogeneous switch reagent.

引用

页码：2476 / 2481

页数：6

共 45 条

[41] A new synthetic approach to functionalize pyrimido[4,5-b]quinoline-2,4(1H,3H)-diones via a three-component one-pot reaction
Aknin, Karen
Desbene-Finck, Stephanie
Helissey, Philippe
Giorgi-Renault, Sylviane
MOLECULAR DIVERSITY, 2010, 14 (01) : 123 - 130
[42] A new synthetic approach to functionalize pyrimido[4,5-b]quinoline-2,4(1H,3H)-diones via a three-component one-pot reaction
Karen Aknin
Stéphanie Desbène-Finck
Philippe Helissey
Sylviane Giorgi-Renault
Molecular Diversity, 2010, 14 : 123 - 130
[43] Chemoselective one-pot access to benzo[e]indole-4,5-diones and naphtho[2,1-b]thiophene-4,5-diones via copper-catalyzed oxidative [3+2] annulation of α-oxoketene N,S-acetals/β-ketothioamides with α-/β-naphthols
Yadav, Dhananjay
Shukla, Gaurav
Ansari, Monish A.
Srivastava, Abhijeet
Singh, Maya Shankar
TETRAHEDRON, 2018, 74 (40) : 5920 - 5931
[44] Novel and efficient synthesis of 4,7-dihydro-1H-pyrrolo[2,3-b] pyridine derivatives via one-pot, three-component approach from N-substituted 5-amino-3-cyanopyrroles, various carbonyl and active methylene compounds
Vilches-Herrera, Marcelo
Spannenberg, Anke
Langer, Peter
Iaroshenko, Viktor O.
TETRAHEDRON, 2013, 69 (29) : 5955 - 5967
[45] Synthesis of 5H-Pyrrolo[3,4-b]Pyridin-5-Ones via a Cerium Chloride Catalyzed Multicomponent Cascade Process: A One-Pot Approach Incorporating Ugi-Zhu 3CR, Aza Diels-Alder, N-Acylation, and Aromatization Reactions
Duraisamy, Ramasamy
Reddy, M. B. Madhusudana
Asharani, I. V.
Thirumalai, Dhakshanamurthy
POLYCYCLIC AROMATIC COMPOUNDS, 2024,

← 1 2 3 4 5 →