EPR in Research of the Magnetic Properties of Spin-Crossover Fe(III) Complexes with Polydentate Schiff Bases

被引：1

作者：

Frolova, E. N. ^{[1
]}

Turanova, O. A. ^{[1
]}

Bazan, L. V. ^{[1
]}

Ovchinnikov, I. V. ^{[1
]}

Turanov, A. N. ^{[1
]}

机构：

[1] RAS, Zavoisky Phys Tech Inst, FRC Kazan Sci Ctr, Kazan, Russia

来源：

APPLIED MAGNETIC RESONANCE | 2024年 / 55卷 / 09期

关键词：

ELECTRON-PARAMAGNETIC-RESONANCE; HIGH-FIELD EPR; EQUILIBRIUM BEHAVIOR; IRON(III) COMPLEXES; PF6; TRANSITION; FEATURES; SPECTRA; LIGAND;

D O I：

10.1007/s00723-024-01685-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Schiff bases allow the creation of compounds with a wide variety of architectures and properties and have been of interest to researchers for many years. This mini-review describes some of the possibilities of the EPR method, which we use to study Fe(III) complexes with polydentate Schiff bases, many of which have been synthesized for the first time. Obtaining information at the local level using EPR spectroscopy allows us to grasp the molecular structure-property relationship and to adjust the synthesis strategy to create multifunctional substances with predetermined properties.

引用

页码：987 / 1010

页数：24

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