Application progresses of carbon materials in magnesium-based solid-state hydrogen storage materials

被引：0

作者：

Zhou R. ^{[1
]}

Liu M. ^{[1
,2
]}

Xue X. ^{[1
]}

Fan Y. ^{[1
]}

Wang S. ^{[1
,2
]}

Kong F. ^{[1
,2
]}

机构：

[1] State Key Laboratory of Bio-based Materials for Green Paper Making, Qilu University of Technology, Shandong Academy of Sciences, Jinan

[2] Key Laboratory of Pulp and Paper Science and Technology, Ministry of Education, Qilu University of Technology, Shandong Academy of Sciences, Jinan

来源：

Zhongguo Youse Jinshu Xuebao/Chinese Journal of Nonferrous Metals | 2024年 / 34卷 / 01期

基金：

中国国家自然科学基金;

关键词：

carbon materials; hydrogen absorption and desorption; hydrogen storage; kinetic modifications; magnesium-based hydrogen storage materials; thermodynamic;

D O I：

10.11817/j.ysxb.1004.0609.2023-44207

中图分类号：

学科分类号：

摘要：

The Mg-based hydrogen storage materials are considered as one of the most promising solid-state hydrogen storage materials due to their high theoretical hydrogen storage density (MgH2, 7.6%), wide source and low cost. However, the high enthalpy of hydrogen release of MgH2 (75 kJ/mol) leads to high hydrogen release temperature (＞380 ℃), poor kinetic and thermodynamic properties, which limit their further application and development in the field of solid-state hydrogen storage. In recent years, carbon materials have been widely used as catalysts or nano-limited carriers for magnesium-based hydrogen storage materials to improve hydrogen absorption and discharge temperature, cycle performance and activation energy, due to the advantages of structural diversification, high tunability, large specific surface area, high mechanical properties and strong electron transport ability. In this paper, it is mainly focused on the research status of carbon materials in magnesium-based hydrogen storage materials, summarizing the modification methods of carbon materials, especially the progress of carbon materials with different dimensions in the field of magnesium-based hydrogen storage applications. Moreover, the future development direction of magnesium-based hydrogen storage materials was prospected. © 2024 Central South University of Technology. All rights reserved.

引用

页码：63 / 76

页数：13

共 62 条

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