Synthesis,Structure,andLuminescentPropertyofa3-DStrontiumComplex[Sr3(pda)2(Hpda)2(H2O)2]_n·2nH2O

被引:3
|
作者
陈砚美 [1 ,2 ]
高倩 [1 ]
高丹丹 [2 ]
王德荣 [2 ]
李亚红 [1 ]
刘玮 [1 ]
李武 [2 ]
机构
[1] Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry,Chemical Engineering and Materials Science, Soochow University
[2] Key Laboratory of Salt Lake Resources and Chemistry,Qinghai Institute of Salt Lakes, Chinese Academy of
关键词
D O I
暂无
中图分类号
O627.2 [第Ⅱ族元素有机化合物];
学科分类号
摘要
The title complex [Sr3(pda)2(Hpda)2(H2O)2]n·2nH2O(H2pda = pyridine-2,6-dicar- boxylic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group P21/c with a = 10.3795(8), b = 9.2225(7), c = 18.5726(14) , β = 104.377(2)o, V = 1722.2(2) 3, C28H22N4O20Sr3, Mr = 997.36, Z = 2, Dc = 1.923 g/cm3, μ = 4.722 mm-1, F(000) = 984, the final R = 0.0269 and wR = 0.0538. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by carboxylate groups. The luminescent property of the title complex has been investigated.
引用
收藏
页码:746 / 752
页数:7
相关论文
共 50 条
  • [21] Synthesis, Crystal Structure and Photoluminescence of [Gd(C6NO2H5)3-(H2O)2]2n•(nH5O2)(nHgCl5)(2nHgCl4)•(2nH2O)
    Chen Wen-Tong
    Huang Jin-Shun
    Fang Xiao-Niu
    Xu Ya-Ping
    Luo Qiu-Yan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (10) : 1270 - 1274
  • [22] Synthesis, crystal structure and magnetic behaviour of {[Co(dimb)2(H2O)2] • (NO3)2 • (H2O)2}n
    Yao, Jing-Cai
    Zhang, Li
    Wang, Yu-Fang
    Ma, Lu-Fang
    Wang, Li-Ya
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (10): : 1648 - 1650
  • [23] SynthesisandStructuralCharacterizationofaNovelCoordinationPolymer[Cd(C4H2O4)(C3H4N2)3]_n·2nH2O
    YUE Lin ZHOU QiuXiang WANG YanJi ZHAO XinQiang Department of Chemical Engineering and Technology Hebei University of Technology Tianjin China
    结构化学, 2005, (03) : 287 - 290+250
  • [24] Synthesis and characterization of strontium 1,3,5-benzenetricarboxylate, [Sr3(1,3,5-BTC)2(H2O)4]•H2O
    Tran, Dat T.
    Chu, Deryn
    Oliver, Allen G.
    Oliver, Scott R. J.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (05) : 351 - 354
  • [25] The solid-state thermal decomposition of Sr3[La(C2O4)3(H2O)2]2•11H2O
    Deb, Nidhuban
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 114 (01) : 261 - 267
  • [26] Excess electron binding by (H2O)2, (H2O)3, H2O...NH3, and H2O...HCl.
    Gutowski, MS
    Skurski, P
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U357 - U357
  • [27] HydrothermalSynthesisandStructureof[Mn(C8H5NO4)·H2O]_n·2nH2O
    廖秋霞
    姚元根
    结构化学, 2006, (04) : 465 - 468
  • [28] Synthesis and crystal structure of [{Zn(3-SBA)(2,2′-bipy)(H2O)2}•H2O]n
    Li, WG
    Wang, ZW
    Cai, Y
    Xu, ZJ
    Li, YZ
    Zheng, HG
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (12) : 1857 - 1860
  • [29] Synthesis, structure and properties of [Pr(C6H5NO2)3(H2O)2]2n•(nHSO2)(nHgCl5)(2nHgCl4)•(2nH2O)
    Chen, Wen-Tong
    JOURNAL OF MOLECULAR STRUCTURE, 2011, 992 (1-3) : 102 - 105
  • [30] Synthesis, Crystal Structure, and Photoluminescent and Semiconductive Properties of [La(C6NO2H5)3(H2O)2]2n•(nH5O2)(nHgCl5)(2nHgCl4)•(2nH2O)
    Chen Wen-Tong
    Huang Jin-Shun
    Liu Dong-Sheng
    Liu Jiu-Hui
    Ying Shao-Ming
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (11) : 1299 - 1304