Synthesis, Crystal Structure and Property of Cu Pb2(OH)2Cl3

被引：1
|
作者：
黄荣荣 [1 ,2 ]
张素允 [2 ]
崔美艳 [2 ]
徐军 [1 ]
何长振 [2 ]
机构：
[1] College of Materials Science and Engineering, Wuhan Institute of Technology
[2] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
来源：
结构化学 | 2015年 / 34卷 / 04期
关键词：
oxyhalide; crystal structure; hydrothermal reaction; semiconductor;
D O I：
暂无
中图分类号：
O627.12 [铜族金属有机化合物];
学科分类号：
摘要：
A new copper(I)-lead(II) oxyhalide, Cu Pb2(OH)2Cl3, has been prepared by hydrothermal reaction and structurally characterized by single-crystal X-ray analysis. The compound crystallizes in tetragonal, space group I4(1)/acd with a = b = 13.77(1), c = 15.38(1) , V = 2916.2(2), Z = 4, Mr = 618.29, Dc = 5.633 g/cm3, μ = 49.97(2) mm-1, F(000) = 4192, the final R = 0.0204 and w R = 0.0452 for 757 observed reflections with I > 2σ(I). The structure of Cu Pb2(OH)2Cl3 contains one-dimensional helical chains built by Cu Cl4 tetrahedra with corner-sharing along the c-axis, in which the Pb2+ and OH- ions are located at the voids between chains. Optical reflectance spectrum measurements indicate that it is a semiconductor with a band-gap of 3.23 e V.
引用
收藏
页码：594 / 598
页数：5
相关论文
共 50 条
  • [31] Hydrothermal Synthesis, Crystal Structure and Luminescent Property of Pb(cbba)2(phen)2
    Wang Qing-Wei
    Li Xiu-Mei
    Wang Zhi-Tao
    Liu Bo
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (11) : 2101 - 2104
  • [32] Stereoactive lone-pair behavior of Pb in the crystal structure of bideauxite:: Pb(2+)2Ag+Cl3F(OH)
    Cooper, MA
    Hawthorne, FC
    Merlino, S
    Pasero, M
    Perchiazzi, N
    CANADIAN MINERALOGIST, 1999, 37 : 915 - 921
  • [33] Crystal structure of Pb-3(IO4(OH)(2))(2)
    Weil, Matthias
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 14 - +
  • [34] Hydrothermal Synthesis and Crystal Structure of Nitrate Phosphate Pb2[PO4](NO3)⋅H2O
    Belokoneva, E. L.
    Volkov, A. S.
    Govorko, N. B.
    Dimitrova, O. V.
    CRYSTALLOGRAPHY REPORTS, 2023, 68 (07) : 1084 - 1088
  • [35] Hydrothermal Synthesis and Crystal Structure of Nitrate Phosphate Pb2[PO4](NO3)⋅H2O
    E. L. Belokoneva
    A. S. Volkov
    N. B. Govorko
    O. V. Dimitrova
    Crystallography Reports, 2023, 68 : 1084 - 1088
  • [36] Crystal structure refinement of mendipite, Pb3O2Cl2
    Pasero, M
    Vacchiano, D
    NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE, 2000, (12): : 563 - 569
  • [37] ON THE CRYSTAL STRUCTURE OF PB2CL2CO3 (PHOSGENITE) AND PB2BR2CO3
    SILLEN, LG
    PETTERSSON, R
    ARKIV FOR KEMI MINERALOGI OCH GEOLOGI, 1946, 21 (05): : 1 - 9
  • [38] The crystal structure of arsentsumebite, Pb2Cu[(As,S)O4]2(OH)
    Zubkova, NV
    Pushcharovsky, DY
    Giester, G
    Tillmanns, E
    Pekov, IV
    Kleimenov, DA
    MINERALOGY AND PETROLOGY, 2002, 75 (1-2) : 79 - 88
  • [39] The crystal structure of arsentsumebite, Pb2Cu[As,S)O4)]2(OH)
    Zubkova, N. V.
    Pushcharovsky, D. Yu.
    Giester, G.
    Tillmanns, E.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2000, 56 : S360 - S360
  • [40] The crystal structure of arsentsumebite, Pb2Cu[(As, S)O4]2(OH)
    N. V. Zubkova
    D. Yu. Pushcharovsky
    G. Giester
    E. Tillmanns
    I. V. Pekov
    D. A. Kleimenov
    Mineralogy and Petrology, 2002, 75 : 79 - 88
12345