A Novel Dinuclear Copper(Ⅱ) Complex: Synthesis, Crystal Structure, Properties and Hirshfeld Surface Analysis

被引：4
|
作者：
张冲 [1 ]
杨莉 [1 ]
陈浩 [1 ]
张淑华 [1 ]
机构：
[1] Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials,Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology (College of Chemistry and Bioengineering),Guilin University of Technology
来源：
结构化学 | 2017年 / 36卷 / 11期
关键词：
N; O-Schiff-base ligand; in-situ oxidation reaction; magnetic properties; Hirshfeld surfaces analysis;
D O I：
暂无
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
摘要：
A novel copper complex [Cu(L)(DMF)](1, HL =(1 Z,N?Z)-3,5-dibromo-N?-((3,5-dibromo-2-hydroxyphenyl)(hydroxy)methylene)-2-hydroxybenzohydrazonic acid which was synthesized by in-situ oxidation reaction derived from Hhdb(Hhdb = 6,6?-((1 E,1?E)-hydrazine-1,2-diylidenebis(methanylylidene)) bis(2,4-dibromophenol)) has been synthesized and characterized by IR, elemental analysis(CHN), TG and single-crystal X-ray diffraction. The single crystal belongs to monoclinic system, space group P21/c with a = 13.538(1), b = 3.912(1), c = 23.778(1) ?, β = 105.232(5)o, Mr = 857.08, V = 1214.9(1) ?~3, Z = 2, Dc = 2.343 g/cm~3, F(000) = 824, μ = 8.375 mm, R = 0.0566, and w R = 0.1610. Compound 1 displays weak anti-ferromagnetic interactions through a η~1:η~1:η~1:η~1:η~1:η~1:μ-Lbridging mode. Hirshfeld surface analysis revealed that complex 1 was supported mainly by Br···H and H···H intermolecular interactions.
引用
收藏
页码：1904 / 1911
页数：8
相关论文
共 50 条
  • [21] Synthesis, characterization, crystal structure, hirshfeld surface analysis and chromotropic properties of halo- bridged copper(II) complexes
    Shirvan, Atie
    Golchoubian, Hamid
    Rezaee, Ehsan
    POLYHEDRON, 2024, 249
  • [22] Synthesis,Crystal Structure,Spectroscopic Characterization,Thermal Stability and Magnetic Properties of a Dinuclear Copper(Ⅱ) Complex
    LI Wei
    LI Chang-Hong
    LI Heng-Feng
    TAN Xiong-Wen
    结构化学, 2015, 34 (05) : 794 - 798
  • [23] Synthesis and Crystal Structure of an Acetate Radical Bridged Dinuclear Copper(Ⅱ) Complex
    DU QiaoYun MA Liang QIN JianHua Department of ChemistryLuoyang Normal UniversityLuoyang China
    结构化学, 2007, (03) : 347 - 351
  • [24] Synthesis and Crystal Structure of an Acetate Radical Bridged Dinuclear Copper(Ⅱ) Complex
    DU Qiao-Yun MA Liang QIN Jian-Hua (Department of Chemistry
    Chinese Journal of Structural Chemistry, 2007, (03) : 347 - 351
  • [25] Crystal structure and hirshfeld surface analysis of novel pyrazole derivatives
    Kumara, Karthik
    Naveen, S.
    Lokanath, N. K.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2017, 73 : C663 - C663
  • [26] Synthesis, crystal structure, DFT calculations, molecular docking study and Hirshfeld surface analysis of alkoxido-bridged dinuclear iron(III) complex
    Akhtar, Muhammad Nadeem
    AlDamen, Murad A.
    Zierkiewicz, Wiktor
    Michalczyk, Mariusz
    Khalid, Muhammad
    Idrisi, Mantasha
    Shahid, M.
    RESEARCH ON CHEMICAL INTERMEDIATES, 2020, 46 (09) : 4155 - 4171
  • [27] Synthesis, crystal structure, DFT calculations, molecular docking study and Hirshfeld surface analysis of alkoxido-bridged dinuclear iron(III) complex
    Muhammad Nadeem Akhtar
    Murad A. AlDamen
    Wiktor Zierkiewicz
    Mariusz Michalczyk
    Muhammad Khalid
    Mantasha Idrisi
    M. Shahid
    Research on Chemical Intermediates, 2020, 46 : 4155 - 4171
  • [28] Synthesis, Crystal Structure and Fluorescent Properties of Dinuclear Zinc Complex
    Bi, Chenglu
    Li, Weihua
    Lu, Hui
    Zhang, Hui
    Sun, Jianhua
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (03) : 761 - 763
  • [29] Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties
    Nour Elleuch
    Donia Fredj
    Nassira Chniba-Boudjada
    Mohamed Boujelbene
    Journal of Inorganic and Organometallic Polymers and Materials, 2020, 30 : 889 - 898
  • [30] Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties
    Elleuch, Nour
    Fredj, Donia
    Chniba-Boudjada, Nassira
    Boujelbene, Mohamed
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2020, 30 (03) : 889 - 898
12345