PI-CATION RADICAL GENERATION VIA AERIAL OXIDATION OF A PORPHYRIN

被引：17
|
作者：
MILGROM, LR [1 ]
FLITTER, WD [1 ]
SHORT, EL [1 ]
机构：
[1] BRUNEL UNIV,DEPT BIOCHEM,UXBRIDGE UB8 3PH,MIDDX,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 11期
关键词：
D O I：
10.1039/c39910000788
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
ESR spectroscopy and simulation suggest that meso-tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphyrin 1 undergoes aerial oxidation in acidified solutions to give a long-lived pi-cation radical with a quasi-2A2u ground state.
引用
收藏
页码：788 / 790
页数：3
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