PI-CATION RADICAL GENERATION VIA AERIAL OXIDATION OF A PORPHYRIN

被引：17

作者：

MILGROM, LR ^{[1
]}

FLITTER, WD ^{[1
]}

SHORT, EL ^{[1
]}

机构：

[1] BRUNEL UNIV,DEPT BIOCHEM,UXBRIDGE UB8 3PH,MIDDX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 11期

关键词：

D O I：

10.1039/c39910000788

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ESR spectroscopy and simulation suggest that meso-tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphyrin 1 undergoes aerial oxidation in acidified solutions to give a long-lived pi-cation radical with a quasi-2A2u ground state.

引用

页码：788 / 790

页数：3

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