REACTIONS OF PHOSPHORYLATED ALLENES WITH DITHIOCARBAMATES

被引:1
|
作者
KHUSAINOVA, NG
SUPPEL, IY
CHERKASOV, RA
PUDOVIK, AN
机构
来源
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1990年 / 39卷 / 04期
关键词
D O I
10.1007/BF00960349
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The addition of morpholino-, piperidino-, and N,N-diethyldithiocarbamate anions to 1,2-propadiene- and 1,2-butadienephosphonates proceeds on the electrophilic 1,2-double bond of the allene system with the formation of linear dithioesters. 1-Vinylallenylphosphonates add dithiocarbamate anions on the 1,3-conjugated system of multiple bonds, forming a mixture of stereoisomeric dithioesters with a diene structure. © 1990 Plenum Publishing Corporation.
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页码:798 / 802
页数:5
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