HYDROGEN-PEROXIDE AS AN ELECTRON-ACCEPTOR IN THE PHOTOOXIDATION OF FERROCENE DERIVATIVES

被引：2
|
作者：
LOGAN, SR
机构：
[1] Department of Applied Physical Sciences, University of Ulster
来源：
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE | 1990年 / 167卷
关键词：
Electron acceptor; Ferrocene; Hydrogen peroxide; Photo-oxidation;
D O I：
10.1524/zpch.1990.167.Part_1.041
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It has been shown that photo-excited -ferrocenyl alkylcarboxylates may undergo oxidation by electron transfer to a molecule of H2O2, in a reaction of comparable efficiency to the corresponding electron transfer reaction to N2O. The study has taken account of the fact that at the wavelengths in the u. v. required for this photo-oxidation, H2O2 also absorbs and its photolysis produces the OH radical, which brings about the same oxidation process. © by R. Oldenbourg Verlag
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页码：41 / 46
页数：6
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