SYNTHESES AND ELECTRICAL-PROPERTIES OF ORGANOSILICON POLYMERS CONTAINING THIOPHENE AND ANTHRAQUINONE UNITS

被引：5
|
作者：
YI, SH
OHASHI, S
SATO, H
NOMORI, H
机构：
[1] TOKYO UNIV AGR & TECHNOL, FAC TECHNOL, KOGANEI, TOKYO 184, JAPAN
[2] KONICA CORP, DEPT TECH PLANNING, HACHIOJI, TOKYO 192, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 04期
关键词：
D O I：
10.1246/bcsj.66.1244
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Organosilicon polymers containing thiophene and anthraquinone units in the main chain were synthesized using palladium catalyst. These polymers were soluble and showed a small UV absorption change by the substituents on the silicon atom. Some of the polymers exhibit cation doping (n-doping) by the electrochemical reduction, and this doping process seemed to depend on the kinds of substituents on silicon atom. These polymers showed electrical conductivity of 3 x 10(-5) S cm-1 when doped with sodium naphthalenide.
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收藏
页码：1244 / 1247
页数：4
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