A DINUCLEAR COPPER(II) COMPLEX OF DEPROTONATED N,N'-BIS(N-PROPYLGLYCYL)-ETHYLENEDIAMINE

被引：0
|
作者：
TAHIROV, TH
LU, TH
SHU, KL
CHUNG, CS
HUANG, CC
HONG, YS
机构：
[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN
[2] CHUNG CHENG INST TECHNOL,DEPT APPL CHEM,TAHSI 33508,TAIWAN
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷
关键词：
D O I：
10.1107/S010827019300722X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title crystal of bis[mu-N,N'-bis(N-propylglycyl-kappaN)ethylenediaminato-kappaN:kappaO']bis[aquacopper(II)] diperchlorate, [Cu2(C12H25N4O2)2(H2O)2](ClO4)2, the cation exists as a dinuclear complex. Each Cu(II) ion is pentacoordinated in a distorted square-pyramid conformation: two donor N atoms of one tetradentate ligand and one N atom and one O atom of the other ligand form a slightly distorted equatorial plane and a water 0 atom occupies the axial position.
引用
收藏
页码：204 / 206
页数：3
相关论文
共 50 条
  • [21] POLAROGRAPHIC STUDIES OF COPPER(II) COMPLEXES WITH N,N'-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE-N,N'-DIACETIC ACID
    MATSUO, T
    MASUDA, Y
    SEKIDO, E
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 160 (1-2): : 169 - 184
  • [22] Bis[bis(ethylenediamine-N,N′)(μN,S-thiocyanato)nickel(II)] bis(hexafluorophosphate)
    James, M
    Kawaguchi, H
    Tatsumi, K
    Hambley, TW
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1809 - 1811
  • [23] CRYSTAL AND MOLECULAR-STRUCTURE OF COPPER(II) COMPLEX OF N,N,N',N'-TETRAKIS(2-HYDROXYPROPYL)ETHYLENEDIAMINE
    ORAMA, O
    ORAMA, M
    SCHUBERT, U
    FINNISH CHEMICAL LETTERS, 1979, (05): : 136 - 139
  • [24] ONNO TETRADENTATE N,N'-BIS(ACETOACETANILIDE)ETHYLENEDIAMINE COMPLEXES OF COBALT(II), COPPER(II), CADMIUM(II) AND MERCURY(II)
    MAHAPATRA, BB
    PUJARI, SK
    TRANSITION METAL CHEMISTRY, 1983, 8 (04) : 202 - 204
  • [25] Synthesis and characterization of N, N′-bis(salicylidene) ethylenediamine Copper complex for dye sensitized solar cells
    Sobhi, Hany
    Ghann, William
    Uddin, Jamal
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [26] Diaquabis(ethylenediamine-κ2N,N′)copper(II) bis(4-fluorobenzoate)
    Li, ZD
    Tan, MY
    Zhu, HL
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1081 - M1083
  • [27] Structure and Magnetic Properties of Bis(μ-azido) bis [N,N′-bis(2-pyridylmethyl) ethylenediamine] dinickel (II) complex
    Gao, EQ
    Liao, DZ
    Jiang, ZH
    Yan, SP
    Zhang, SF
    ACTA CHIMICA SINICA, 2001, 59 (08) : 1294 - 1298
  • [28] SYNTHESIS AND STRUCTURE OF A TETRANUCLEAR ZINC(II) COMPLEX OF N,N'-DIMETHYL-N,N'-BIS(BETA-MERCAPTOETHYL)ETHYLENEDIAMINE
    HU, WJ
    BARTON, D
    LIPPARD, SJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (04) : 1170 - 1173
  • [29] [N,N′-bis(2-furylmethylene)ethylenediamine]dichlorozinc(II)
    Wang, W
    Li, J
    Du, GX
    Zhang, FX
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M334 - M335
  • [30] COPPER(II) AND NICKEL(II) WITH N,N '-BIS(SALICYLIDENE)THIOSEMICARBAZIDE HETEROMETAL COMPLEX COMPOUNDS
    Panchenko, Tetiana
    Evseeva, Maria
    Ranskiy, Anatoliy
    CHEMISTRY & CHEMICAL TECHNOLOGY, 2014, 8 (03): : 243 - 248
12345