PREPARATION OF COBALT(II) COMPLEXES OF BETA-KETO-ESTERS

被引：5

作者：

HARRIS, PG

HOUGHTON, RP

TAYLOR, PL

机构：

[1] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,POB 912,CARDIFF CF1 3TB,WALES

[2] ICI PAINTS,SLOUGH SL2 5DS,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 22期

关键词：

D O I：

10.1016/S0277-5387(00)83601-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using the ethyl. (-)-menthyl and (1-methyl-2-methoxy)ethyl esters of 3-keto-butanoic acid as model compounds, three procedures have been developed for preparing cobalt(II) complexes of beta-keto esters in non-aqueous media. These procedures involve the reaction between the lithium enolate, the caesium enolate and the trimethylsilyl enolate of the beta-keto ester with an appropriate cobalt(II) compound. All three procedures appear applicable to the preparation of other metal(II) complexes and to beta-diketones.

引用

页码：2957 / 2960

页数：4

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