ASYMMETRIC-SYNTHESIS OF AMINES USING A CHIRAL, NON-RACEMIC, CYCLIC SULFINAMIDE

被引：12
|
作者：
HOSE, DRJ
RAYNHAM, T
WILLS, M
机构：
[1] UNIV BATH,SCH CHEM,CLAVERTON DOWN,BATH BA2 7AY,AVON,ENGLAND
[2] ROCHE PROD LTD,WELWYN GARDEN CIT AL7 3AY,HERTS,ENGLAND
来源：
TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 10期
关键词：
D O I：
10.1016/S0957-4166(00)80065-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The homochiral cyclic sulphinamide S(S)R-(+)-1 has been employed in the asymmetric synthesis of alpha-methylbenzylamine via the benzylidene sulphinamide R(S)R-(-)-3. Following diastereoselective reduction and hydrolysis S(S)R-(+)-1 can be recycled in one step from the sulphinic acid 6.
引用
收藏
页码：2159 / 2162
页数：4
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