C59N+ AND C69N+ - ISOELECTRONIC HETEROANALOGUES OF C-60 AND C-70

被引：133
|
作者：
LAMPARTH, I [1 ]
NUBER, B [1 ]
SCHICK, G [1 ]
SKIEBE, A [1 ]
GROSSER, T [1 ]
HIRSCH, A [1 ]
机构：
[1] UNIV KARLSRUHE,INST ORGAN CHEM,D-76131 KARLSRUHE,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 20期
关键词：
FULLERENES; HETEROFULLERENES; MASS SPECTROMETRY;
D O I：
10.1002/anie.199522571
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fragmentation reactions in the mass spectrometer were used to generate the first characterized nitrogen heterofullerene ions C59N+ and C69N+ from regioselectively synthesized oligoiminofullerenes. During this process one carbon atom in the fullerene core is removed and replaced with a nitrogen atom. C59N+ (shown on the right) has almost the same structure as the isoelectronic C60. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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收藏
页码：2257 / 2259
页数：3
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