A NOVEL ALLYLIC OXIDATION USING A COMBINATION OF FORMIC-ACID AND SELENIUM DIOXIDE

被引：41
|
作者：
SHIBUYA, K
机构：
[1] Tokyo Research Laboratories, Kowa Co., Ltd., 2-17-43 Noguchi-cho
来源：
SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 20期
关键词：
D O I：
10.1080/00397919408010614
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A combination of formic acid and selenium dioxide in dioxane has been found to be an efficient system for the allylic oxygenation of olefins, in particular for sterically hindered ones, leading to the corresponding allylic alcohols or formates.
引用
收藏
页码：2923 / 2941
页数：19
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