SULFUR-MEDIATED (OR SELENIUM)-MEDIATED SYNTHESIS OF METHANOANTHRACENE DERIVATIVES - THE FIRST SYNTHESIS OF A SELENO-CYANOHYDRIN

被引：6

作者：

PELLOUX, N ^{[1
]}

VALLEE, Y ^{[1
]}

DUCHENET, V ^{[1
]}

机构：

[1] UNIV CAEN,ISMRA,LCT,CNRS,URA 480,F-14050 CAEN,FRANCE

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 89卷 / 1-4期

关键词：

9,10-DIHYDRO-9,10-METHANOANTHRACENE; WITTIG REARRANGEMENT; SELENO-CYANOHYDRINE; DIELS-ALDER ADDUCTS; THIOALDEHYDES; ANTHRACENE DERIVATIVES;

D O I：

10.1080/10426509408020427

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A synthesis of thio- and seleno-substituted 9,10-dihydro-9,10-methanoanthracene derivatives is reported. They are obtained by Wittig rearrangement from 11-thia and 11-selena-9,10-dihydro-9,10-ethanoanthracene derivatives. This rearrangement is applied to the first synthesis of a seleno-cyanohydrin (R(1)R(2)C(SeH)CN).

引用

页码：17 / 23

页数：7

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