HETEROCYCLES FROM NITRILE IMINES .4. CHIRAL 4,5-DIHYDRO-1,2,4-TRIAZIN-6-ONES

被引：0
|
作者：
ELABADELAH, MM
HUSSEIN, AQ
THAHER, BA
机构：
来源：
HETEROCYCLES | 1991年 / 32卷 / 10期
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D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of nitrile imines (II) with alpha-amino esters (III) proceeds with no detectable racemization and constitutes a convenient synthetic route to 4,5-dihydro-1,2,4-triazin-6-ones (IV). Permanganate oxidation of the heterocycles (IV) affords the corresponding 1,2,4-triazin-6-ones (V). The reaction of (II) with beta-amino esters gives the respective acyclic amidrazone adducts (VI).
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页码：1879 / 1895
页数：17
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