SELRESOLV - INVERSE AND SELECTIVE DETECTION OF LONG-RANGE C,H SPIN COUPLING-CONSTANTS

被引：22
|
作者：
OCHS, M [1 ]
BERGER, S [1 ]
机构：
[1] UNIV MARBURG,FACHBEREICH CHEM,HANS MEERWEIN STR,W-3550 MARBURG,GERMANY
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 1990年 / 28卷 / 11期
关键词：
Inverse detection; Long‐range J(CH) coupling; Selective excitation;
D O I：
10.1002/mrc.1260281115
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A pulse sequence (SELRESOLV) for the proton‐detected determination of long‐range C,H coupling constants is described. The 2D J(HH) resolved experiment with selective 13C excitation separates J(HH) from J(CH) couplings. Application is demonstrated using crotonaldehyde and β‐naphthol as examples. Copyright © 1990 John Wiley & Sons, Ltd.
引用
收藏
页码：994 / 997
页数：4
相关论文
共 50 条
  • [21] LONG-RANGE C-13 - H-1 COUPLING-CONSTANTS .3. METHYLPYRIDINES
    TAKEUCHI, Y
    ORGANIC MAGNETIC RESONANCE, 1975, 7 (04): : 181 - 184
  • [22] SIGNS OF LONG-RANGE SPIN-SPIN COUPLING-CONSTANTS IN METHYL PYRIDINES AS DETERMINED BY INDOR TECHNIQUE
    KOWALEWSKI, VJ
    CONTRERAS, RH
    JOURNAL OF MAGNETIC RESONANCE, 1972, 8 (01) : 101 - +
  • [23] LONG-RANGE CARBON-PROTON AND CARBON-CARBON SPIN-SPIN COUPLING-CONSTANTS
    MARSHALL, JL
    MIILLER, DE
    CONN, SA
    SEIWELL, R
    IHRIG, AM
    ACCOUNTS OF CHEMICAL RESEARCH, 1974, 7 (10) : 333 - 339
  • [24] A DISCO APPROACH TO THE MEASUREMENT OF HETERONUCLEAR LONG-RANGE COUPLING-CONSTANTS
    NUZILLARD, JM
    BERNASSAU, JM
    JOURNAL OF MAGNETIC RESONANCE SERIES B, 1994, 103 (03): : 284 - 287
  • [25] LONG-RANGE CARBON-PROTON COUPLING-CONSTANTS IN PYRIDINE
    MIYAJIMA, G
    TAKAHASH.K
    SUGIYAMA, H
    ORGANIC MAGNETIC RESONANCE, 1974, 6 (03): : 181 - 183
  • [26] ASSESSMENT OF A METHOD FOR THE MEASUREMENT OF LONG-RANGE HETERONUCLEAR COUPLING-CONSTANTS
    RICHARDSON, JM
    TITMAN, JJ
    KEELER, J
    NEUHAUS, D
    JOURNAL OF MAGNETIC RESONANCE, 1991, 93 (03): : 533 - 553
  • [27] CONFORMATIONAL STUDIES OF OLIGOSACCHARIDES FROM LONG-RANGE H-1-C-13 COUPLING-CONSTANTS MEASURED BY H-1 DETECTION
    YAN, ZY
    BUSH, CA
    BIOPHYSICAL JOURNAL, 1990, 57 (02) : A242 - A242
  • [28] SELECTIVE INVERSE MULTIPLE BOND ANALYSIS - A SIMPLE 1D-EXPERIMENT FOR THE MEASUREMENT OF LONG-RANGE HETERONUCLEAR COUPLING-CONSTANTS
    CROUCH, RC
    MARTIN, GE
    JOURNAL OF MAGNETIC RESONANCE, 1991, 92 (01): : 189 - 194
  • [29] LONG-RANGE C-13-H-1 COUPLING-CONSTANTS .4. METHOXYPYRIDINE, AMINOPYRIDINE AND HYDROXYPYRIDINE
    TAKEUCHI, Y
    DENNIS, N
    ORGANIC MAGNETIC RESONANCE, 1975, 7 (05): : 244 - 246
  • [30] USE OF LONG-RANGE C-13-H-1 COUPLING-CONSTANTS FOR STRUCTURAL ASSIGNMENTS OF JUGLONE DERIVATIVES
    CASTILLO, G
    ELLAMES, GJ
    OSBORNE, AG
    SAMMES, PG
    JOURNAL OF CHEMICAL RESEARCH-S, 1978, (02): : 45 - &
12345