OXIDATION OF MOLYBDENUM AND TUNGSTEN METALS BY MOLYBDENUM AND TUNGSTEN HEXAFLUORIDES IN ACETONITRILE - PREPARATION OF THE 1-1 PENTAFLUORIDE ACETONITRILE COMPLEXES

被引：9

作者：

BAO, N

WINFIELD, JM

机构：

[1] Department of Chemistry, University of Glasgow, Glasgow

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 50卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)84999-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Molybdenum and tungsten metal powders are oxidized by their respective hexafluorides in the presence of acetonitrile at room temperature to give the 1:1 pentafluoride, acetonitrile complexes, MF5.NCMe, M = Mo or W. Their i.r. spectra are consistent with C4v symmetry for the MF5N moiety. The tungsten pentafluoride complex appears to be stable with respect to disproportionation at room temperature.

引用

页码：339 / 343

页数：5

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