N-methyl, N-tert.butyl amino ethyl methacrylate was synthesized by ring opening reaction of N-methyl, N-tert.butyl aziridinium triflate and sodium methacrylate. This new monomer was polymerized free radically and also with redox system to give telechelic polymer with pendent amino groups in the polymer back bone. The chemical structure of the monomer and the polymer was determined by IR spectroscopy, H-1-NMR and elemental analysis technique.
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Massachusetts Gen Hosp, Howard Hughes Med Inst, Boston, MA 02114 USA
Massachusetts Gen Hosp, Ctr Computat & Integrat Biol, Simches Res Ctr, Boston, MA 02114 USAMassachusetts Gen Hosp, Howard Hughes Med Inst, Boston, MA 02114 USA
Subtelny, Alexander O.
Hartman, Matthew C. T.
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Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA
Virginia Commonwealth Univ, Massey Canc Ctr, Richmond, VA 23284 USAMassachusetts Gen Hosp, Howard Hughes Med Inst, Boston, MA 02114 USA
Hartman, Matthew C. T.
Szostak, Jack W.
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Massachusetts Gen Hosp, Howard Hughes Med Inst, Boston, MA 02114 USA
Massachusetts Gen Hosp, Ctr Computat & Integrat Biol, Simches Res Ctr, Boston, MA 02114 USAMassachusetts Gen Hosp, Howard Hughes Med Inst, Boston, MA 02114 USA