Crystal structure of 2-cyano-1-methyl-pyridinium perchlorate

被引:1
|
作者
Nguyen, Vu D. [1 ]
McCormick, Cameron A. [1 ]
Mague, Joel T. [2 ]
Koplitz, Lynn V. [1 ]
机构
[1] Loyola Univ, Dept Chem, New Orleans, LA 70118 USA
[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
关键词
crystal structure; salt; pyridinium; perchlorate; hydrogen bonding;
D O I
10.1107/S2056989015019155
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title salt, C7H7N2+center dot ClO4-, comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supramolecular layers are stabilized and connected by C-H center dot center dot center dot O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridinium-perchlorate N center dot center dot center dot O contact [2.867 (5) angstrom] is noted. The crystal was refined as an inversion twin.
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页码:O852 / U448
页数:9
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