HEADSPACE ANALYSIS OF 1,4-DIOXANE IN PRODUCTS CONTAINING POLYETHOXYLATED SURFACTANTS BY GC-MS

被引：25
|
作者：
RASTOGI, SC
机构：
[1] National Environmental Research Institute, Division of Environmental Chemistry, Ministry of Environment, Søborg, DK-2860
来源：
CHROMATOGRAPHIA | 1990年 / 29卷 / 9-10期
关键词：
1,4-dioxane; Gas chromatography-mass spectrometry; Headspace analysis; Polyethoxylated surfactants;
D O I：
10.1007/BF02261391
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
A headspace, gas chromatography-mass spectrometric (GC-MS) method for the identification and quantitation of 1,4-dioxane in polyethoxylated surfactants is described. An isotope dilution method employing 1,4-d8-dioxane has been used for the quantitation of 1,4-dioxane which is based on the determination of the molecular ion (mass 88) by MS. The detection limit of the method was 0.3 ppm 1,4-dioxane. 82% of the cosmetic products investigated were found to contain 0.3-96 ppm 1,4-dioxane, and 85% of the products for dish washing investigated contained 1.8-65 ppm 1,4-dioxane. © 1990 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH.
引用
收藏
页码：441 / 445
页数：5
相关论文
共 50 条
  • [21] Ab Initio conformational analysis of 1,4-dioxane
    Chapman, DM
    Hester, RE
    JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (18): : 3382 - 3387
  • [22] Development of analytical method for determination of 1,4-dioxane in cleansing products
    Tahara, M.
    Obama, T.
    Ikarashi, Y.
    INTERNATIONAL JOURNAL OF COSMETIC SCIENCE, 2013, 35 (06) : 575 - 580
  • [23] Analysis of 1,4-dioxane in drinking water by headspace solid-phase microextraction-gas chromatography
    Wang Yufei
    Shi Jiawei
    Wang Li
    Jin Micong
    CHINESE JOURNAL OF CHROMATOGRAPHY, 2015, 33 (04) : 441 - 445
  • [24] Screening of biotransformation products of carvone enantiomers by headspace-SPME/GC-MS
    Demirci, F
    Kirimer, N
    Demirci, B
    Noma, Y
    Baser, KHC
    ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES, 2001, 56 (1-2): : 58 - 64
  • [25] PROCEDURES FOR DERIVATIZATION OF PRODUCTS FOR GC-MS ANALYSIS
    不详
    ADVANCES IN PROSTAGLANDIN THROMBOXANE AND LEUKOTRIENE RESEARCH, 1989, 18 : 521 - 544
  • [26] Headspace gas chromatographic determination of 1,4-dioxane with adsorption preconcentration on silica modified with λ-carrageenan
    Fedorchuk, O. I.
    Kobylinska, N. G.
    Zaitsev, V. N.
    JOURNAL OF ANALYTICAL CHEMISTRY, 2017, 72 (03) : 295 - 302
  • [27] Solid-Phase Microextraction (SPME) and Triple Quadrupole Gas Chromatography (GC-MS- MS) - Simultaneous Analysis of VOCs and 1,4-Dioxane in Water
    Egli, Christine
    Pfister, Rolf
    Moffatt, Lorna
    Kelting, Rebecca
    LC GC EUROPE, 2014, 27 (12) : 674 - 674
  • [28] Headspace gas chromatographic determination of 1,4-dioxane with adsorption preconcentration on silica modified with λ-carrageenan
    O. I. Fedorchuk
    N. G. Kobylinska
    V. N. Zaitsev
    Journal of Analytical Chemistry, 2017, 72 : 295 - 302
  • [29] Headspace Trap GC-MS analysis of hop aroma compounds in beer
    Schmidt, C.
    Biendl, M.
    BREWING SCIENCE, 2016, 69 (1-2): : 9 - 15
  • [30] Analysis of volatile organic compounds in fuel oil by headspace GC-MS
    Anyakudo, Felix
    Adams, Erwin
    Van Schepdael, Ann
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2018, 98 (04) : 323 - 337
12345