DETERMINATION OF THALLIUM IN SOIL

A new spectrophotometric method is described for the determination of thallium in soil by extraction of Tl(III) with a toluene solution of N,N'-diphenylbenzamidine after acidification with 0.2-4.0 M HC1, and reaction of the extract with Crystal violet in the presence of 0.01-0.8 M HC1. The value of molar absorptivity of T1(III)-X-CV complex (where X = Cl or Br; CV = Crystal violet) in toluene is 7.00 × 1041 mole−1cm−1at the absorption maximum of 610 nm. The detection limit of the method is 20 ng ml−1. The present method is free from interference of almost metal ions commonly associated with Tl. The method has been applied for analysis of the metal to soils. © 1992, Taylor & Francis Group, LLC. All rights reserved.