SYNTHESIS OF A POLYMER-SUPPORTED O-PHENYLENE(DIPHOSPHINE) AND CHARACTERIZATION OF SOME METAL-COMPLEXES

被引：8
|
作者：
CHAMPNESS, NR
LEVASON, W
OLDROYD, RD
GULLIVER, DJ
机构：
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,ENGLAND
[2] BP CHEM,HULL RES & TECHNOL CTR,KINGSTON HULL HU12 8DS,N HUMBERSIDE,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期
关键词：
NICKEL; PLATINUM; RHODIUM; RUTHENIUM; DIPHOSPHINE; POLYMER; SUPPORTED CATALYST;
D O I：
10.1016/0022-328X(94)87066-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis is described of the polymer-supported diphosphine, PolPP, in which an o-C6H3(PPh(2))(2) unit is linked via a -CH2O group in the 4-position of the benzene ring to a Merrifield resin. The preparations of the complexes (PolPP)NiCl2, (PolPP)PtCl2, (PolPP>Rh(PPh(3))Cl and (PolPP)Ru(PPh(3))Cl-2 and related model compounds are reported, and their characterization by UV-visibIe spectroscopy and metal edge EXAFS is described.
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页码：275 / 281
页数：7
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