SYNTHESIS OF BETA,GAMMA-UNSATURATED D-ALPHA-AMINO ACIDS FROM L-CYSTEINE

被引：27
|
作者：
DUTHALER, RO
机构：
[1] Central Research Laboratories, Ciba-Geigy Ag, Basel, CH-4002, Post Office Box
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 06期
关键词：
D O I：
10.1002/anie.199107051
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
D-alpha-Amino-acids 2 are accessible in high optical purity by acid hydrolysis of the 5-thiazolidinone 1. Compounds of the type 1 can be prepared in a few reaction steps from L-cysteine; during the conversion of 1 into 2 unsaturated residues R remain intact. Boc = tert-butoxycarbonyl.
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页码：705 / 707
页数：3
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