Crystal structure of bis(2-methyl-1H-imidazol-3-ium) tetrachloridocobaltate(II)

被引：5
|
作者：
Diop, Mouhamadou Birame [1 ]
Diop, Libasse [1 ]
Maris, Thierry [2 ]
机构：
[1] Univ Cheikh Anta Diop, Fac Sci & Tech, Dept Chim, Lab Chim Minerale & Analyt, Dakar, Senegal
[2] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; cobalt complex; hydrogen bonds; organic-inorganic hybrid compound;
D O I：
10.1107/S2056989015014127
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, (C4H7N2)(2)[CoCl4], consists of two 2methylimidazolium cations and one tetrahedral [CoCl4](2-) anion. The anions and cations interact through N- H center dot center dot center dot Cl hydrogen bonds to define layers with a stacking direction along [100]. Besides van der Waals forces, weak C-H center dot center dot center dot pi Cl interactions between these layers stabilize the crystal packing.
引用
收藏
页码：1064 / +
页数：7
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