REACTIVITY OF TERT-BUTOXYL RADICALS TOWARDS SUBSTITUTED INDOLE-DERIVATIVES

被引：6

作者：

ENCINAS, MV ^{[1
]}

LISSI, EA ^{[1
]}

MAJMUD, C ^{[1
]}

OLEA, AF ^{[1
]}

机构：

[1] UNIV CHILE,FAC CIENCIAS,DEPT QUIM,SANTIAGO,CHILE

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1991年 / 23卷 / 09期

关键词：

D O I：

10.1002/kin.550230902

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tert-butoxyl radicals react with indole and methyl substituted derivatives by hydrogen abstraction. For those compounds which are unsubstituted at the N-atom, hydrogen abstraction takes place almost exclusively at the N-H bond. The reactivity of these compounds correlates with their donor electron capacity, pointing to significant contribution of charge transfer to the transition state stability. Substitution at the N atom considerably decreases the reactivity.

引用

页码：761 / 766

页数：6

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