METHANOL OXIDATION TO FORMALDEHYDE ON BISMUTH PHOSPHATE-BASED CATALYSTS

被引：14
|
作者：
ABADZHJIEVA, N
TZOKOV, P
UZUNOV, I
MINKOV, V
KLISSURSKI, D
RIVES, V
机构：
[1] BULGARIAN ACAD SCI,INST ORGAN CHEM,BU-1113 SOFIA,BULGARIA
[2] UNIV SALAMANCA,FAC FARM,DEPT QUIM INORGAN,E-37007 SALAMANCA,SPAIN
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 53卷 / 02期
关键词：
D O I：
10.1007/BF02073050
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A bismuth (III) phosphate catalyst has been prepared by precipitation and characterized by X-ray diffraction, thermogravimetric analysis, and X-ray photoelectron and infrared spectroscopy. Its activity and selectivity toward selective methanol oxidation to formaldehyde has been studied by a flow method. A high selectivity has been found, similar to that reported for typical catalysts used for this reaction. The possible importance of the strength and covalency of the P-O bonds is discussed.
引用
收藏
页码：413 / 418
页数：6
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