SYNTHESIS AND X-RAY STRUCTURE OF A NOVEL CAVITY-CONTAINING DINUCLEAR NICKEL(II) COMPLEX

被引:0
|
作者
GOSLING, PA [1 ]
SIJBESMA, RP [1 ]
SPEK, AL [1 ]
NOLTE, RJM [1 ]
机构
[1] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,3584 CH UTRECHT,NETHERLANDS
来源
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1993年 / 112卷 / 06期
关键词
EPOXIDATION; NICKEL(II) SALEN MANGANESE(III) SALEN; METALLOHOST;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Compounds consisting of a substrate-binding site and a Ni(II) or Mn(III) salen moiety have been synthesized. These compounds are able to epoxidise a variety of alkenes in the presence of sodium hypochlorite or iodosylbenzene. The X-ray structure of the nickel(II) complex is reported.
引用
收藏
页码:404 / 406
页数:3
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