SYNTHESIS AND X-RAY STRUCTURE OF A NOVEL CAVITY-CONTAINING DINUCLEAR NICKEL(II) COMPLEX

被引：0

作者：

GOSLING, PA ^{[1
]}

SIJBESMA, RP ^{[1
]}

SPEK, AL ^{[1
]}

NOLTE, RJM ^{[1
]}

机构：

[1] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,3584 CH UTRECHT,NETHERLANDS

来源：

RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1993年 / 112卷 / 06期

关键词：

EPOXIDATION; NICKEL(II) SALEN MANGANESE(III) SALEN; METALLOHOST;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compounds consisting of a substrate-binding site and a Ni(II) or Mn(III) salen moiety have been synthesized. These compounds are able to epoxidise a variety of alkenes in the presence of sodium hypochlorite or iodosylbenzene. The X-ray structure of the nickel(II) complex is reported.

引用

页码：404 / 406

页数：3

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