EFFECT OF ION-PAIRING ON THE KINETICS OF AQUATION OF BROMOPENTAMMINECOBALT(III) PERCHLORATE IN DICARBOXYLATE-ACETATE MEDIA

被引：0

作者：

ZAGHLOUL, AA

ELSHAZLY, SA

KHALIL, MM

AMIRA, MF

机构：

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1995年 / 34卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetics of aquation of [Co(NH3)5Br]2+ in different types of dicarboxylate solutions containing acetone (10%, v/v), at different temperatures have been investigated in the light of the effects of ion-pairing on reaction rates and mechanism. A new empirical correlation between the rate coefficient and the stoichiometric concentration of the ion-pairing dicarboxylate ligand (C1) has been established and a reaction mechanism is proposed.

引用

页码：52 / 54

页数：3

共 48 条

[31] SYNTHESIS, CHARACTERIZATION, AND AQUATION KINETICS OF [N-(O-CARBOXYPHENYL)-IMINODIACETATO](GLYCINATO)CHROMATE(III) COMPLEX ION IN ACIDIC MEDIA
CHATTERJEE, C
PHADKE, SV
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (09): : 2095 - 2098
[32] Kinetics and mechanism of the oxidation of oxalic acid and bioxalate ion by [ethylenebis(bignanide)] silver (III) cation in aqueous perchlorate media
Mukhopadhyay, S
Kundu, S
Banerjee, R
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1995, 107 (04): : 403 - 410
[33] KINETICS AND MECHANISM OF THE OXIDATION OF OXALATE ION BY TRIS(ACETYLACETONATO)MANGANESE(III) AND ITS HYDROLYTIC DERIVATIVES IN AQUEOUS PERCHLORATE-MEDIA
MUKHOPADHYAY, S
CHAUDHURI, S
DAS, R
BANERJEE, R
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1993, 71 (12): : 2155 - 2159
[34] SUBSTITUTION REACTIONS OF OXALATO COMPLEX IONS .2. KINETICS OF AQUATION OF TRISOXALATOCHROMIUM(III) ION-SOLVENT DEUTERIUM ISOTOPE EFFECT
KRISHNAMURTY, KV
HARRIS, GM
JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (03): : 346 - 349
[35] Kinetics of aquation of trans-dichlorobis(N,N′-dimethylethylenediamine)cobalt(III) ion in water–methanol in water–propan-2-ol media
Gehan M. El-Subruiti
Salah S. Massoud
Transition Metal Chemistry, 1997, 22 : 14 - 18
[36] STUDY OF THE EFFECT OF ION-PAIRING ON THE KINETICS OF CO-13 EXCHANGE WITH CO-12 IN THE CLUSTER ANION [HRU3(CO)11]-
PAYNE, MW
LEUSSING, DL
SHORE, SG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 309 - INOR
[37] KINETICS AND MECHANISM OF OXIDATION OF HYPOPHOSPHITE ION BY DIAQUOBIS(PENTANE-2,4-DIONATO)MANGANESE(III) IN AQUEOUS PERCHLORATE-MEDIA
BANERJEE, R
DAS, R
CHAKRABURTTY, AK
TRANSITION METAL CHEMISTRY, 1992, 17 (04) : 277 - 279
[38] Kinetics of aquation of trans-dichlorobis(N,N'-dimethylethylenediamine)cobalt(III) ion in water-methanol and in water-propan-2-ol media
ElSubruiti, GM
Massoud, SS
TRANSITION METAL CHEMISTRY, 1997, 22 (01) : 14 - 18
[39] ION-PAIRING EFFECT ON THE AQUATION KINETICS OF [CO(PY)4CL2]X (X=CL-, NO-3-, IO-4-, CLO-4-, SCN- AND N-3-) IN DIFFERENT SOLVENT SYSTEMS - BASICITY MEASUREMENT OF THE COUNTER ION
KEBEDE, Z
RETTA, N
TRANSITION METAL CHEMISTRY, 1990, 15 (06) : 417 - 420
[40] KINETICS OF THE UNCATALYZED AND SILVER(I)-CATALYZED OXIDATION OF HYDROGEN-PEROXIDE BY [ETHYLENEBIS(BIGUANIDE)]SILVER(III) ION IN ACID PERCHLORATE-MEDIA
BANERJEE, R
DAS, A
DASGUPTA, S
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (09): : 1645 - 1649

← 1 2 3 4 5 →