Promotion effect of KF on the basic properties of ZrO2

被引:0
|
作者
Zhu, JH
Kabashima, H
Hattori, H
Kita, H
机构
[1] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
[2] Hokkaido Univ, Grad Sch Environm Earth Sci, Div Mat Sci, Sapporo, Hokkaido 060, Japan
[3] Hokkaido Univ, Ctr Adv Res Energy Technol, Sapporo, Hokkaido 060, Japan
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Basicity of ZrO2 is enhanced by KF modification due to the reaction of KF with ZrO2 surface: KF + ZrO2 --> K2ZrF6 + KOH. After pretreated above 673K, KF/ZrO2 catalyst exhibited higher activity for 1-butene isomerization at 273K than ZrO2. The amount of basic sites strongly adsorbing CO2 in the form of bicarbonate was also increased.
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页码:1005 / 1008
页数:4
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