A CONVENIENT PROTOCOL FOR THE STEREOCONTROLLED SYNTHESIS OF OLEFINS WITH A HOMOALLYLIC TYPE OF FUNCTIONALITY

被引：1
|
作者：
VASILEV, AA
KRYSHTAL, GV
SEREBRYAKOV, EP
机构：
来源：
MENDELEEV COMMUNICATIONS | 1995年 / 02期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A combination of the Horner-Emmons synthesis of alkyl 2,4-dienoates with their hydrogenation over complex L.Cr(CO)(3) catalysts (L = arene or 3CO) provides a versatile, stereocontrolled approach to olefins with a homoallylic pattern of functional substitution, such as certain insect pheromones or (Z)-prenylated arenes analogous to the ''left-side'' moiety of bifurcarenone.
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页码：41 / 42
页数：2
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